Publications

46. “The Borataphenanthrene Anion” Tyler A. Bartholome, Aishvaradeep Kaur, David Wilson, Jason L. Dutton, Caleb D. Martin*, Angew. Chem. Int. Ed., 2020, 59, 11470-11476. Link

45. “Reactions of BCl3 with Diiminopyridine Ligands” John R. Tidwell, Abigail K. Africa, Thomas Dunnam, Caleb D. Martin*, Eur. J. Inorg. Chem., DOI:10.1002/ejic.202000533. (Invited for Special Collection Entitled “Pincer Chemistry and Catalysis”) Link 

44. “Li Deposited on LiCl: An Efficient Reducing Agent” Xiaojun Su, Leif E. Laperriere, Caleb D. Martin*, New. J. Chem., DOI:D0NJ01010C. (Invited for Special Issue Entitled “Boron & Beyond: Celebrating Todd B. Marder’s Contributions to Chemistry”) Link

43. “Dimeric Boroles: Effective Sources of Monomeric Boroles for Heterocycle Synthesis” Xiaojun Su, J. J. Baker, Caleb D. Martin*, Chem. Sci., 2020, 11, 126-131. Link42. “Evaluation of the Sigma Donating and Pi Accepting Properties of N-Heterocyclic Boryl Anions” Lorenzo J. Romeo, Aishvaradeep Kaur, David Wilson*, Caleb D. Martin*, Jason L. Dutton*, Inorg. Chem., 2019, 58, 16500-16509. Link  

41. “Aromaticity of Unsaturated BEC4 Heterocycles (E = N, P, As, Sb, O, S, Se, Te)” Paul A. Brown, Caleb D. Martin, Kevin L. Shuford*, Phys. Chem. Chem. Phys., 2019, 21, 18458-18466. (Featured on the Front Cover) Link

40. “Successive Carbene Insertion into 9-Phenyl-9-Borafluorene” Tyler A. Bartholome, Kristen R. Bluer, Caleb D. Martin*, Dalton Trans., 2019, 48, 6319-6322. (Invited for Special Issue Entitled “Inorganic Chemistry of the p-Block Elements”) Link

39. “Synthesis of 9-Borafluorene Analogues Featuring a 1,1′-Bis(o-carborane) Backbone” S. Yruegas, Jonathan C. Axtell, Kent O. Kirlikovali, Alexander M. Spokoyny, Caleb D. Martin*, Chem. Commun., 2019, 55, 2892-2895. (Featured on the Front Cover) Link

38. “Diverse Reactivity of Dienes with Pentaphenylborole and 1-Phenyl-2,3,4,5-Tetramethylborole Dimer” J. J. Baker, Khadilah H. M. Al-Furaiji, O. Tara Liyanage, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin*, Chem. -Eur. J., 2019, 25, 1581-1587. Link

37. “Investigating the Reactivity of 9-Phenyl-9-Borafluorene with N-H, O-H, P-H, and S-H Bonds” L. E. Laperriere, S. Yruegas, C. D. Martin*, Tetrahedron, 2019, 75, 937-943. (Special Issue on Frustrated Lewis Acids and Organoboranes) Link

36. “Coordination and Ring Expansion of 1,2-Dipolar Molecules with 9-Phenyl-9-Borafluorene” Kristen R. Bluer#, Leif E. Laperriere#, Alba Pujol#, Sam Yruegas, Venkata A. K. Adiraju, Caleb D. Martin*, Organometallics, 2018, 37, 2917-2927. # Equal Contribution Link

35. “Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9-Borafluorene” Sam Yruegas, Jonathan H. Barnard, Khalidah Al-Furaiji, Jason L. Dutton, David J. D. Wilson, Caleb D. Martin*, Organometallics, 2018, 37, 1515-1518. Link

34. “Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis” Cheng-Liang Zhu, Cheng Wang, Qi-Xue Qin, Sam Yruegas, Caleb D. Martin, Hao Xu*, ACS Catalysis, 2018, 8, 5032-5037. Link

33. “Intermolecular Insertion Reactions of Azides Into 9-Borafluorenes to Generate 9,10-B,N-Phenanthrenes” Sam Yruegas, Jesse J. Martinez, Caleb D. Martin*, Chem. Commun., 2018, 54, 6808-6811. (Invited for Special Issue Entitled “Emerging Investigators 2018”) Link

32. “Isomer Dependence on the Reactivity of Diazenes with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin*, Chem. -Eur. J., 2017, 23, 11437-11444. Link

31. “Exploiting Pincer Ligands to Perturb the Geometry at Boron” Kexuan Huang, Jason L. Dutton, Caleb D. Martin*, Chem. -Eur. J., 2017, 23, 10532-10535. Link

30. “C-H Addition Reactivity of 2-Phenylpyridine and 2,2’-Bipyridine with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin*, Dalton Trans., 2017, 46, 10324-10331. Link

29. “Ring Opening of Epoxides Induced by Pentaphenylborole” Sam Yruegas, Charles Wilson, Jason L. Dutton, Caleb D. Martin*, Organometallics, 2017, 36, 2581-2587. (Invited for Special Issue Entitled “Tailoring the Optoelectronic Properties of Organometallic Compounds with Main Group Elements”) Link

28. “Expedient Synthesis of 1,2-Thiaborines via Sulfur Insertion into Boroles” Sam Yruegas, Caleb D. Martin*, Chem. -Eur. J., 2016, 22, 18358-18361. (Selected as a Hot Paper) Link

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27. “Ring Expansion Reactions of Anti-Aromatic Boroles: A Promising Synthetic Avenue to Unsaturated Boracycles” Jonathan H. Barnard, Sam Yruegas, Kexuan Huang, Caleb D. Martin*, Chem. Commun., 2016, 52, 9985-9991. (Featured on the Inside Cover) LinkChemComm9975

26. “Oxygen Insertion into Boroles as a Route to 1,2-Oxaborines” Sam Yruegas, Dayna C. Patterson, Caleb D. Martin*, Chem. Commun., 2016, 52, 6658-6661. (Featured on the Inside Cover) Link

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25. “Reactivity of a Phosphaalkyne with Pentaarylboroles” Jonathan H. Barnard, Sam Yruegas, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin*, Organometallics, 2016, 35, 929-931. Link

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24. “Peculiar Reactivity of Isothiocyanates with Pentaphenylborole” Kexuan Huang, Caleb D. Martin*, Inorg. Chem., 2016, 55, 330-337. Link

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23. “Probing the Reactivity of Pentaphenylborole with N-H, O-H, P-H, and S-H Bonds” Sam Yruegas, Kexuan Huang, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin*, Dalton Trans., 2016, 45, 9902-9911. (Invited for Special Issue Entitled “New Talent: Americas”) Link

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22. “Reactions of Pentaphenylborole with Main Group Hydrides” Ben C. Caputo, Zackery J. Manning, Jonathan H. Barnard, Caleb D. Martin*, Polyhedron, 2016, 114, 273-277. (Invited for Special Issue Entitled “Undergraduate Research in Inorganic Chemistry”) LinkTOC21. “1,2-Phosphaborines: Hybrid Inorganic/Organic P-B Analogues of Benzene” Jonathan H. Barnard, Paul A. Brown, Kevin L. Shuford, Caleb D. Martin*, Angew. Chem. Int. Ed., 2015, 54, 12083-12086. Link

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20. “Reactions of Imines, Nitriles, and Isocyanides with Pentaphenylborole: Coordination, Ring Expansion, C-H Bond Activation, and Hydrogen Migration Reactions” Kexuan Huang, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin*, Inorg. Chem., 2015, 54, 8957-8968. Link

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19. “Ring Expansion Reactions of Pentaphenylborole with Dipolar Molecules as a Route to Seven-Membered Boron Heterocycles” Kexuan Huang, Caleb D. Martin*, Inorg. Chem., 2015, 54, 1869-1875. Link

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18. “Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide” Shannon A. Couchman, Trevor K. Thompson, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin*, Chem. Commun., 2014, 11724-11726. Link

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Post Doctoral Work:
17. “Cross Coupling Reactions between Stable Carbenes” Cory M. Weinstein, Caleb D. Martin, Liu Liu,  Guy Bertrand*, Angew. Chem. Int. Ed., 2014, 53, 6550-6553. Link
16. “Carbene-stabilized main group radicals and radical ions” Caleb D. Martin, Michele Soleilhavoup, Guy Bertrand*, Chem. Sci., 2013, 4, 3020-3030. Link
15. “Exploring the reactivity of white phosphoruswith electrophilic carbenes: synthesis of a P4 cage and P8clusters” Caleb D. Martin, Cory M. Weinstein, Curtis E. Moore, Arnold L. Rheingold, Guy Bertrand*, Chem. Commun., 2013, 49, 4486-4488. Link
14. “31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes” Olivier Back, Martin Henry-Ellinger, Caleb D. Martin, David Martin, Guy Bertrand*, Angew. Chem. Int. Ed.,2013, 52, 2939-2943. Link
Graduate Work:
13. “The syntheses and electrochemical studies of a ferrocene substituted diiminopyridine ligand and its P, S, Se, and Te complexes” Eleanor Magdzinski, Pierrangelo Gobbo, Caleb D. Martin, Mark Workentin, Paul J. Ragogna*, Inorg. Chem., 2012, 51, 8425-8432. Link
12. “Reactions of Diiminopyridine Ligands with Chalcogen Halides” Caleb D. Martin, Paul J. Ragogna, Inorg. Chem., 2012, 51, 2947-2953. Link
11. “Substitution Matters: Isolating Phosphorus Diiminopyridine Complexes” Caleb D. Martin, Paul J. Ragogna, Dalton Trans., 2011, 39, 11976-11980. Link
10. “Oxygen, Sulfur, Selenium, Tellurium and Polonium” Caleb D. Martin, Paul J. Ragogna, Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2011,107, 110-124. Link
9. “A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base” Allison L. Brazeau, Christine A. Caputo, Caleb D. Martin, Nathan D. Jones, Paul J. Ragogna, Dalton Trans., 2010, 39, 11069-11073. Link
8. “Synthesis and Reactivity of Sulfur(II) Dications Stabilized Using Monodentate Ligands” Caleb D. Martin Paul J. Ragogna, Inorg. Chem.,2010,49, 8164-8172. Link
7. “Reactions of a-Diimine Ligands with the In Situ Generated “S(OTf)2” Synthon” Caleb D. Martin and Paul J. Ragogna, Inorg. Chem., 2010, 49, 4324-4330. Link
6. “Remarkably stable chalcogen(II) dications” Caleb D. Martin, Christine M. Le, Paul J. Ragogna, J. Am. Chem. Soc., 2009,131, 15126-15127. Link
5. “Synthesis of N,C Bound Sulfur, Selenium and Tellurium Heterocycles via the Reaction of Chalcogen Halides with –CH3Substituted Diazabutadiene (DAB) Ligands” Jason L. Dutton, Caleb D. Martin, Michael J. Sgro, Nathan D. Jones, Paul J. Ragogna, Inorg. Chem., 2009, 48, 3239-3247. Link
4. “Dicationic Analogues of the N-Heterocyclic Silylene or Phosphenium cation” Caleb D. Martin, Michael J. Ferguson, Michael C. Jennings, Paul J. Ragogna, Angew. Chem. Int. Ed., 2009, 48, 2210-2213. Link
Undergraduate Work:
3. “Bis(m-diethylphosphido-k2P:P)bis[bis(2,4,6-trimethylphenyl)indium(III)Diethylphosphidobis(2,4,6-trimethyl-phenyl)indane dimer” Glen G. Briand, Andreas Decken, Dane A. Knackstedt, Caleb D. Martin,Acta Cryst. E., 2011, 67, m1578. Link
2. “Synthesis and Molecular Structure of trans-Dichlorodi((4-fluorophenyl)methanamine)palladium(II)” Caleb D. Martin, Francis E. Appoh, Christopher M. Vogels, Andreas Decken, Stephen A. Westcott, X-Ray Structure Analysis Online, 2008, 24, x223-x224. Link
1. “Preferred Bonding Motif for Indium-Aminoethanethiolate Complexes: Structural Characterization of (Me2NCH2CH2S)2InX/SR (X = Cl, I; R = 4-MeC6H4S, 4-MeOC6H4S)” Glen G. Briand, Benjamin F. T. Cooper, David B. S. MacDonald, Caleb D. Martin, Gabriele Schatte, Inorg. Chem., 2006, 45, 8423-8429. Link