Publications

69. “The Cyclotriborate Trianion” Manjur O. Akram, Caleb D. Martin,* Chem, Accepted.

68. “Synthesis of Phenanthrylboroles and Formal Nitrene Insertion to Access Azaborapyrenes” Harie Zacharias, Ayesha Begum, Jianhua Han, Tyler A. Bartholome, Todd B. Marder, Caleb D. Martin,* Chem. Commun. 2024, 60, 8740-8743. (Invited for Special Collection Titled “Pioneering Investigators”) Link

67. “Carborane-Arene Fused Boracyclic Analogues of Polycyclic Aromatic Hydrocarbons Accessed by Intramolecular Borylation” Yijie Li,# Masilamani Tamizmani,# Manjur O. Akram, Caleb D. Martin,* Chem. Sci. 2024, 15, 7568-7575. Link

66. “Formation of Strong Boron Lewis Acid Sites on Silica” Kavyasripriya K. Samudrala, Manjur O. Akram, Jason L. Dutton, Caleb D. Martin,* Matthew P. Conley,* Inorg. Chem. 2024, 63, 4939–4946. Link

65. “Single Component Globular Systems Capable of Plastic or Elastic Deformation and Structural Transitions” Sanjay Dutta, Caleb D. Martin,* Cryst. Growth Des. 2023, 23, 8173-8180. Link

64. “Addition of a Phosphinoboronate Ester to Borole and Borafluorene” Manjur O. Akram, Christopher M. Vogels, Webster L. Santos, Stephen A. Westcott, Caleb D. Martin,* Synlett. 2023, 34, 2193-2196. (Invited for Special Issue Titled “Modern Boron Chemistry: 60 years of the Matteson Reaction”) Link

63. “The Effect of Carborane Substituents on the Lewis Acidity of Boranes” Manjur O. Akram, Caleb D. Martin,* Jason Dutton,* Inorg. Chem. 2023, 62, 13495-13504. Link

62. “Examining the Reactivity of Tris(ortho-carboranyl)borane with Lewis Bases and Application in Frustrated Lewis Pair Si-H Bond Cleavage” Kanika Vashisth, Sanjay Dutta, Manjur O. Akram, Caleb D. Martin,* Dalton Trans., 2023, 52, 9639-9645. Link

61. “Bis(1-methyl-ortho-carboranyl)borane” Manjur O. Akram, John Tidwell, Jason Dutton, Caleb D. Martin,* Angew. Chem. Int. Ed., 2023, e202307040. Link

60. “Scrutinizing Formally NiIV Centers through the Lenses of Core Spectroscopy, Molecular Orbital Theory, and Valence Bond Theory” Ida DiMucci, Charles Titus, Dennis Nordlund, James Bour, Eugene Chong, Mikhail Kosobokov, Caleb Martin, Noel Nebra, David Vicic, Sam Yruegas, Samantha MacMillan,* Jason Shearer,* Kyle Lancaster,* Chem. Sci., 2023, 15, 6915-6929. Link

59. “Triple-Decker Iron and Cobalt Complexes Featuring a Bridging 1,2-Diboratabenzene Ligand” Masilamani Tamizmani, John R. Tidwell, Eric W. Reinheimer, Brian M. Lindley, and Caleb D. Martin,* Inorg. Chem., 2023, 62, 7150-7154. Link

58. “Probing B-C Bond Insertion With Gold Acetylide and Azide” Yijie Li, Yu-Hsian Shen, Alec M. Esper, John R. Tidwell, Adam S. Veige, Caleb D. Martin,* Dalton Trans., 2023, 52, 668-674. Link

57. “Assessing the Donor Ability of Boratabenzene and 9-Borataphenanthrene Anions through Metal Complexes with Carbonyl Ligands” Katherine Rojales#, Masilamani Tamizmani#, Tyler A. Bartholome, Caleb D. Martin,* Dalton Trans., 2022, 51, 17216-17223. #Co-first authorship. Link

56. “Tris(ortho-carboranyl)borane: An Isolable, Halogen-Free, Lewis Super Acid” Manjur O. Akram, John Tidwell, Jason Dutton, Caleb D. Martin,* Angew. Chem. Int. Ed., e202212073. Link

55. “A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands” James Vanjak, Branford Wilkins, Veacheslav Vieru, Nattamai Bhuvanesh, Joseph Reibenspies, Caleb Martin, Liviu Chibotaru, Michael Nippe,* J. Am. Chem. Soc. 2022, 144, 17743-17447. Link

54. “An International Study Evaluating Elemental Analysis” Rupert E. H. Kuveke*, Lachlan Barwise, Yara van Ingen, Kanika Vashisth, Nicholas Roberts, Saurabh S. Chitnis,* Jason L. Dutton,* Caleb D. Martin,* Rebecca L. Melen,* ACS Cent. Sci., 2022, 8, 855. Link53. “Accessing Boron-Doped Pentaphene Analogues from 12-Boradibenzofluorene” Manjur O. Akram, John R. Tidwell, Jason L. Dutton, David J. D. Wilson, Andrew Molino, Caleb D. Martin,* Inorg. Chem., 2022, 61, 9595–9604 Link

52. “Investigating the Reactions of BiCl3, Diiminopyridine, and Trimethylsilyl trifluoromethanesulfonate” John R. Tidwell and Caleb D. Martin,* Organometallics, 2022, 41, 1197-1203. Link

51. “Boratabenzene and 9-Borataphenanthrene Ligation to Coinage Metals” Greta K. Wisofsky#, Katherine Rojales#, Xiaojun Su, Tyler A. Bartholome, Andrew Molino, Aishvaryadeep Kaur, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Inorg. Chem., 2021, 60, 18981-18989. #Co-first authorship. Link

50. “Nickel Borolide Complexes and Their Complex Electronic Structure” Sam Yruegas, Hao Tang, Gayle Z. Bornovski, Xiaojun Su, Siyoung Sung, Michael B. Hall,* Michael Nippe,* Caleb D. Martin,* Inorg. Chem., 2021, 60, 16160-16167. Link

49. “Antimony Diiminopyridine Complexes” John R. Tidwell, Jason L. Dutton, Caleb D. Martin,* Dalton Trans., 2021, 50, 11716-11719. Link

48. “Borataalkene Hydrofunctionalization Reactions” Tyler A. Bartholome, Jesse J. Martinez, Aishveryadeep Kaur, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2021, 40, 1966-1973. Link

47. “9-Borafluorenes: Synthesis, Properties, and Reactivity” Xiaojun Su#, Tyler A. Bartholome#, John R. Tidwell, Alba Pujul, Sam Yruegas, Jesse J. Martinez, Caleb D. Martin,* Chem. Rev., 2021, 121, 4147-4192. #Co-first authorship Link

46. “Li Deposited on LiCl: An Efficient Reducing Agent” Xiaojun Su, Leif E. Laperriere, Caleb D. Martin,* New. J. Chem., 2021, 45, 14913-14915. (Invited for Special Issue Entitled “Boron & Beyond: Celebrating Todd B. Marder’s Contributions to Chemistry”) Link

45. “Reactions of BCl3 with Diiminopyridine Ligands” John R. Tidwell, Abigail K. Africa, Thomas Dunnam, Caleb D. Martin,* Eur. J. Inorg. Chem., 2020, 2955-2957. (Invited for Special Collection Entitled “Pincer Chemistry and Catalysis”) Link 44. “The Borataphenanthrene Anion” Tyler A. Bartholome, Aishvaradeep Kaur, David Wilson, Jason L. Dutton, Caleb D. Martin,* Angew. Chem. Int. Ed., 2020, 59, 11470-11476. Link43. “Dimeric Boroles: Effective Sources of Monomeric Boroles for Heterocycle Synthesis” Xiaojun Su, J. J. Baker, Caleb D. Martin,* Chem. Sci., 2020, 11, 126-131. Link42. “Evaluation of the Sigma Donating and Pi Accepting Properties of N-Heterocyclic Boryl Anions” Lorenzo J. Romeo, Aishvaradeep Kaur, David Wilson,* Caleb D. Martin,* Jason L. Dutton,* Inorg. Chem., 2019, 58, 16500-16509. Link  

41. “Aromaticity of Unsaturated BEC4 Heterocycles (E = N, P, As, Sb, O, S, Se, Te)” Paul A. Brown, Caleb D. Martin, Kevin L. Shuford,* Phys. Chem. Chem. Phys., 2019, 21, 18458-18466. (Featured on the Front Cover) Link

40. “Successive Carbene Insertion into 9-Phenyl-9-Borafluorene” Tyler A. Bartholome, Kristen R. Bluer, Caleb D. Martin,* Dalton Trans., 2019, 48, 6319-6322. (Invited for Special Issue Entitled “Inorganic Chemistry of the p-Block Elements”) Link

39. “Synthesis of 9-Borafluorene Analogues Featuring a 1,1′-Bis(o-carborane) Backbone” S. Yruegas, Jonathan C. Axtell, Kent O. Kirlikovali, Alexander M. Spokoyny, Caleb D. Martin,* Chem. Commun., 2019, 55, 2892-2895. (Featured on the Front Cover) Link

38. “Diverse Reactivity of Dienes with Pentaphenylborole and 1-Phenyl-2,3,4,5-Tetramethylborole Dimer” J. J. Baker, Khadilah H. M. Al-Furaiji, O. Tara Liyanage, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Chem. -Eur. J., 2019, 25, 1581-1587. Link

37. “Investigating the Reactivity of 9-Phenyl-9-Borafluorene with N-H, O-H, P-H, and S-H Bonds” L. E. Laperriere, S. Yruegas, C. D. Martin,* Tetrahedron, 2019, 75, 937-943. (Special Issue on Frustrated Lewis Acids and Organoboranes) Link

36. “Coordination and Ring Expansion of 1,2-Dipolar Molecules with 9-Phenyl-9-Borafluorene” Kristen R. Bluer#, Leif E. Laperriere#, Alba Pujol#, Sam Yruegas, Venkata A. K. Adiraju, Caleb D. Martin,* Organometallics, 2018, 37, 2917-2927. # Equal Contribution Link

35. “Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9-Borafluorene” Sam Yruegas, Jonathan H. Barnard, Khalidah Al-Furaiji, Jason L. Dutton, David J. D. Wilson, Caleb D. Martin,* Organometallics, 2018, 37, 1515-1518. Link

34. “Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis” Cheng-Liang Zhu, Cheng Wang, Qi-Xue Qin, Sam Yruegas, Caleb D. Martin, Hao Xu,* ACS Catalysis, 2018, 8, 5032-5037. Link

33. “Intermolecular Insertion Reactions of Azides Into 9-Borafluorenes to Generate 9,10-B,N-Phenanthrenes” Sam Yruegas, Jesse J. Martinez, Caleb D. Martin,* Chem. Commun., 2018, 54, 6808-6811. (Invited for Special Issue Entitled “Emerging Investigators 2018”) Link

32. “Isomer Dependence on the Reactivity of Diazenes with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin,* Chem. -Eur. J., 2017, 23, 11437-11444. Link

31. “Exploiting Pincer Ligands to Perturb the Geometry at Boron” Kexuan Huang, Jason L. Dutton, Caleb D. Martin,* Chem. -Eur. J., 2017, 23, 10532-10535. Link

30. “C-H Addition Reactivity of 2-Phenylpyridine and 2,2’-Bipyridine with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin,* Dalton Trans., 2017, 46, 10324-10331. Link

29. “Ring Opening of Epoxides Induced by Pentaphenylborole” Sam Yruegas, Charles Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2017, 36, 2581-2587. (Invited for Special Issue Entitled “Tailoring the Optoelectronic Properties of Organometallic Compounds with Main Group Elements”) Link

28. “Expedient Synthesis of 1,2-Thiaborines via Sulfur Insertion into Boroles” Sam Yruegas, Caleb D. Martin,* Chem. -Eur. J., 2016, 22, 18358-18361. (Selected as a Hot Paper) Link

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27. “Ring Expansion Reactions of Anti-Aromatic Boroles: A Promising Synthetic Avenue to Unsaturated Boracycles” Jonathan H. Barnard, Sam Yruegas, Kexuan Huang, Caleb D. Martin,* Chem. Commun., 2016, 52, 9985-9991. (Featured on the Inside Cover) LinkChemComm9975

26. “Oxygen Insertion into Boroles as a Route to 1,2-Oxaborines” Sam Yruegas, Dayna C. Patterson, Caleb D. Martin,* Chem. Commun., 2016, 52, 6658-6661. (Featured on the Inside Cover) Link

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25. “Reactivity of a Phosphaalkyne with Pentaarylboroles” Jonathan H. Barnard, Sam Yruegas, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2016, 35, 929-931. Link

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24. “Peculiar Reactivity of Isothiocyanates with Pentaphenylborole” Kexuan Huang, Caleb D. Martin,* Inorg. Chem., 2016, 55, 330-337. Link

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23. “Probing the Reactivity of Pentaphenylborole with N-H, O-H, P-H, and S-H Bonds” Sam Yruegas, Kexuan Huang, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Dalton Trans., 2016, 45, 9902-9911. (Invited for Special Issue Entitled “New Talent: Americas”) Link

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22. “Reactions of Pentaphenylborole with Main Group Hydrides” Ben C. Caputo, Zackery J. Manning, Jonathan H. Barnard, Caleb D. Martin,* Polyhedron, 2016, 114, 273-277. (Invited for Special Issue Entitled “Undergraduate Research in Inorganic Chemistry”) LinkTOC21. “1,2-Phosphaborines: Hybrid Inorganic/Organic P-B Analogues of Benzene” Jonathan H. Barnard, Paul A. Brown, Kevin L. Shuford, Caleb D. Martin,* Angew. Chem. Int. Ed., 2015, 54, 12083-12086. Link

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20. “Reactions of Imines, Nitriles, and Isocyanides with Pentaphenylborole: Coordination, Ring Expansion, C-H Bond Activation, and Hydrogen Migration Reactions” Kexuan Huang, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Inorg. Chem., 2015, 54, 8957-8968. Link

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19. “Ring Expansion Reactions of Pentaphenylborole with Dipolar Molecules as a Route to Seven-Membered Boron Heterocycles” Kexuan Huang, Caleb D. Martin,* Inorg. Chem., 2015, 54, 1869-1875. Link

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18. “Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide” Shannon A. Couchman, Trevor K. Thompson, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Chem. Commun., 2014, 11724-11726. Link

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Post Doctoral Work:
17. “Cross Coupling Reactions between Stable Carbenes” Cory M. Weinstein, Caleb D. Martin, Liu Liu,  Guy Bertrand,* Angew. Chem. Int. Ed., 2014, 53, 6550-6553. Link
16. “Carbene-stabilized main group radicals and radical ions” Caleb D. Martin, Michele Soleilhavoup, Guy Bertrand,* Chem. Sci., 2013, 4, 3020-3030. Link
15. “Exploring the reactivity of white phosphoruswith electrophilic carbenes: synthesis of a P4 cage and P8clusters” Caleb D. Martin, Cory M. Weinstein, Curtis E. Moore, Arnold L. Rheingold, Guy Bertrand,* Chem. Commun., 2013, 49, 4486-4488. Link
14. “31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes” Olivier Back, Martin Henry-Ellinger, Caleb D. Martin, David Martin, Guy Bertrand,* Angew. Chem. Int. Ed.,2013, 52, 2939-2943. Link
Graduate Work:
13. “The syntheses and electrochemical studies of a ferrocene substituted diiminopyridine ligand and its P, S, Se, and Te complexes” Eleanor Magdzinski, Pierrangelo Gobbo, Caleb D. Martin, Mark Workentin, Paul J. Ragogna,* Inorg. Chem., 2012, 51, 8425-8432. Link
12. “Reactions of Diiminopyridine Ligands with Chalcogen Halides” Caleb D. Martin, Paul J. Ragogna, Inorg. Chem., 2012, 51, 2947-2953. Link
11. “Substitution Matters: Isolating Phosphorus Diiminopyridine Complexes” Caleb D. Martin, Paul J. Ragogna, Dalton Trans., 2011, 39, 11976-11980. Link
10. “Oxygen, Sulfur, Selenium, Tellurium and Polonium” Caleb D. Martin, Paul J. Ragogna, Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2011,107, 110-124. Link
9. “A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base” Allison L. Brazeau, Christine A. Caputo, Caleb D. Martin, Nathan D. Jones, Paul J. Ragogna, Dalton Trans., 2010, 39, 11069-11073. Link
8. “Synthesis and Reactivity of Sulfur(II) Dications Stabilized Using Monodentate Ligands” Caleb D. Martin Paul J. Ragogna, Inorg. Chem.,2010,49, 8164-8172. Link
7. “Reactions of a-Diimine Ligands with the In Situ Generated “S(OTf)2” Synthon” Caleb D. Martin and Paul J. Ragogna, Inorg. Chem., 2010, 49, 4324-4330. Link
6. “Remarkably stable chalcogen(II) dications” Caleb D. Martin, Christine M. Le, Paul J. Ragogna, J. Am. Chem. Soc., 2009,131, 15126-15127. Link
5. “Synthesis of N,C Bound Sulfur, Selenium and Tellurium Heterocycles via the Reaction of Chalcogen Halides with –CH3Substituted Diazabutadiene (DAB) Ligands” Jason L. Dutton, Caleb D. Martin, Michael J. Sgro, Nathan D. Jones, Paul J. Ragogna, Inorg. Chem., 2009, 48, 3239-3247. Link
4. “Dicationic Analogues of the N-Heterocyclic Silylene or Phosphenium cation” Caleb D. Martin, Michael J. Ferguson, Michael C. Jennings, Paul J. Ragogna, Angew. Chem. Int. Ed., 2009, 48, 2210-2213. Link
Undergraduate Work:
3. “Bis(m-diethylphosphido-k2P:P)bis[bis(2,4,6-trimethylphenyl)indium(III)Diethylphosphidobis(2,4,6-trimethyl-phenyl)indane dimer” Glen G. Briand, Andreas Decken, Dane A. Knackstedt, Caleb D. Martin,Acta Cryst. E., 2011, 67, m1578. Link
2. “Synthesis and Molecular Structure of trans-Dichlorodi((4-fluorophenyl)methanamine)palladium(II)” Caleb D. Martin, Francis E. Appoh, Christopher M. Vogels, Andreas Decken, Stephen A. Westcott, X-Ray Structure Analysis Online, 2008, 24, x223-x224. Link
1. “Preferred Bonding Motif for Indium-Aminoethanethiolate Complexes: Structural Characterization of (Me2NCH2CH2S)2InX/SR (X = Cl, I; R = 4-MeC6H4S, 4-MeOC6H4S)” Glen G. Briand, Benjamin F. T. Cooper, David B. S. MacDonald, Caleb D. Martin, Gabriele Schatte, Inorg. Chem., 2006, 45, 8423-8429. Link