68. “Synthesis of Phenanthrylboroles and Formal Nitrene Insertion to Access Azaborapyrenes” Harie Zacharias, Ayesha Begum, Jianhua Han, Tyler A. Bartholome, Todd B. Marder, Caleb D. Martin,* Chem. Commun. Accepted. (Invited for Special Collection Titled “Pioneering Investigators”) Link
67. “Carborane-Arene Fused Boracyclic Analogues of Polycyclic Aromatic Hydrocarbons Accessed by Intramolecular Borylation” Yijie Li,# Masilamani Tamizmani,# Manjur O. Akram, Caleb D. Martin,* Chem. Sci. 2024, 15, 7568-7575. Link
66. “Formation of Strong Boron Lewis Acid Sites on Silica” Kavyasripriya K. Samudrala, Manjur O. Akram, Jason L. Dutton, Caleb D. Martin,* Matthew P. Conley,* Inorg. Chem. 2024, 63, 4939–4946. Link
65. “Single Component Globular Systems Capable of Plastic or Elastic Deformation and Structural Transitions” Sanjay Dutta, Caleb D. Martin,* Cryst. Growth Des. 2023, 23, 8173-8180. Link
64. “Addition of a Phosphinoboronate Ester to Borole and Borafluorene” Manjur O. Akram, Christopher M. Vogels, Webster L. Santos, Stephen A. Westcott, Caleb D. Martin,* Synlett. 2023, 34, 2193-2196. (Invited for Special Issue Titled “Modern Boron Chemistry: 60 years of the Matteson Reaction”) Link
63. “The Effect of Carborane Substituents on the Lewis Acidity of Boranes” Manjur O. Akram, Caleb D. Martin,* Jason Dutton,* Inorg. Chem. 2023, 62, 13495-13504. Link
62. “Examining the Reactivity of Tris(ortho-carboranyl)borane with Lewis Bases and Application in Frustrated Lewis Pair Si-H Bond Cleavage” Kanika Vashisth, Sanjay Dutta, Manjur O. Akram, Caleb D. Martin,* Dalton Trans., 2023, 52, 9639-9645. Link
61. “Bis(1-methyl-ortho-carboranyl)borane” Manjur O. Akram, John Tidwell, Jason Dutton, Caleb D. Martin,* Angew. Chem. Int. Ed., 2023, e202307040. Link
60. “Scrutinizing Formally NiIV Centers through the Lenses of Core Spectroscopy, Molecular Orbital Theory, and Valence Bond Theory” Ida DiMucci, Charles Titus, Dennis Nordlund, James Bour, Eugene Chong, Mikhail Kosobokov, Caleb Martin, Noel Nebra, David Vicic, Sam Yruegas, Samantha MacMillan,* Jason Shearer,* Kyle Lancaster,* Chem. Sci., 2023, 15, 6915-6929. Link
59. “Triple-Decker Iron and Cobalt Complexes Featuring a Bridging 1,2-Diboratabenzene Ligand” Masilamani Tamizmani, John R. Tidwell, Eric W. Reinheimer, Brian M. Lindley, and Caleb D. Martin,* Inorg. Chem., 2023, 62, 7150-7154. Link
58. “Probing B-C Bond Insertion With Gold Acetylide and Azide” Yijie Li, Yu-Hsian Shen, Alec M. Esper, John R. Tidwell, Adam S. Veige, Caleb D. Martin,* Dalton Trans., 2023, 52, 668-674. Link
57. “Assessing the Donor Ability of Boratabenzene and 9-Borataphenanthrene Anions through Metal Complexes with Carbonyl Ligands” Katherine Rojales#, Masilamani Tamizmani#, Tyler A. Bartholome, Caleb D. Martin,* Dalton Trans., 2022, 51, 17216-17223. #Co-first authorship. Link
56. “Tris(ortho-carboranyl)borane: An Isolable, Halogen-Free, Lewis Super Acid” Manjur O. Akram, John Tidwell, Jason Dutton, Caleb D. Martin,* Angew. Chem. Int. Ed., e202212073. Link
55. “A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands” James Vanjak, Branford Wilkins, Veacheslav Vieru, Nattamai Bhuvanesh, Joseph Reibenspies, Caleb Martin, Liviu Chibotaru, Michael Nippe,* J. Am. Chem. Soc. 2022, 144, 17743-17447. Link
54. “An International Study Evaluating Elemental Analysis” Rupert E. H. Kuveke*, Lachlan Barwise, Yara van Ingen, Kanika Vashisth, Nicholas Roberts, Saurabh S. Chitnis,* Jason L. Dutton,* Caleb D. Martin,* Rebecca L. Melen,* ACS Cent. Sci., 2022, 8, 855. Link53. “Accessing Boron-Doped Pentaphene Analogues from 12-Boradibenzofluorene” Manjur O. Akram, John R. Tidwell, Jason L. Dutton, David J. D. Wilson, Andrew Molino, Caleb D. Martin,* Inorg. Chem., 2022, 61, 9595–9604 Link
52. “Investigating the Reactions of BiCl3, Diiminopyridine, and Trimethylsilyl trifluoromethanesulfonate” John R. Tidwell and Caleb D. Martin,* Organometallics, 2022, 41, 1197-1203. Link
51. “Boratabenzene and 9-Borataphenanthrene Ligation to Coinage Metals” Greta K. Wisofsky#, Katherine Rojales#, Xiaojun Su, Tyler A. Bartholome, Andrew Molino, Aishvaryadeep Kaur, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Inorg. Chem., 2021, 60, 18981-18989. #Co-first authorship. Link
50. “Nickel Borolide Complexes and Their Complex Electronic Structure” Sam Yruegas, Hao Tang, Gayle Z. Bornovski, Xiaojun Su, Siyoung Sung, Michael B. Hall,* Michael Nippe,* Caleb D. Martin,* Inorg. Chem., 2021, 60, 16160-16167. Link
49. “Antimony Diiminopyridine Complexes” John R. Tidwell, Jason L. Dutton, Caleb D. Martin,* Dalton Trans., 2021, 50, 11716-11719. Link
48. “Borataalkene Hydrofunctionalization Reactions” Tyler A. Bartholome, Jesse J. Martinez, Aishveryadeep Kaur, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2021, 40, 1966-1973. Link
47. “9-Borafluorenes: Synthesis, Properties, and Reactivity” Xiaojun Su#, Tyler A. Bartholome#, John R. Tidwell, Alba Pujul, Sam Yruegas, Jesse J. Martinez, Caleb D. Martin,* Chem. Rev., 2021, 121, 4147-4192. #Co-first authorship Link
46. “Li Deposited on LiCl: An Efficient Reducing Agent” Xiaojun Su, Leif E. Laperriere, Caleb D. Martin,* New. J. Chem., 2021, 45, 14913-14915. (Invited for Special Issue Entitled “Boron & Beyond: Celebrating Todd B. Marder’s Contributions to Chemistry”) Link
45. “Reactions of BCl3 with Diiminopyridine Ligands” John R. Tidwell, Abigail K. Africa, Thomas Dunnam, Caleb D. Martin,* Eur. J. Inorg. Chem., 2020 . (Invited for Special Collection Entitled “Pincer Chemistry and Catalysis”) Link 44. “The Borataphenanthrene Anion” Tyler A. Bartholome,
43. “Dimeric Boroles: Effective Sources of Monomeric Boroles for Heterocycle Synthesis” Xiaojun Su, J. J. Baker, Caleb D. Martin,* Chem. Sci., 2020, 11, 126-131. Link
42. “Evaluation of the Sigma Donating and Pi Accepting Properties of N-Heterocyclic Boryl Anions”
41. “Aromaticity of Unsaturated BEC4 Heterocycles (E = N, P, As, Sb, O, S, Se, Te)” Paul A. Brown, Caleb D. Martin, Kevin L. Shuford,* Phys. Chem. Chem. Phys., 2019, 21, 18458-18466. (Featured on the Front Cover) Link
40. “Successive Carbene Insertion into 9-Phenyl-9-Borafluorene” Tyler A. Bartholome, Kristen R. Bluer, Caleb D. Martin,* Dalton Trans., 2019, 48, 6319-6322. (Invited for Special Issue Entitled “Inorganic Chemistry of the p-Block Elements”) Link
39. “Synthesis of 9-Borafluorene Analogues Featuring a 1,1′-Bis(o-carborane) Backbone” S. Yruegas, Jonathan C. Axtell, Kent O. Kirlikovali, Alexander M. Spokoyny, Caleb D. Martin,* Chem. Commun., 2019, 55, 2892-2895. (Featured on the Front Cover) Link
38. “Diverse Reactivity of Dienes with Pentaphenylborole and 1-Phenyl-2,3,4,5-Tetramethylborole Dimer” J. J. Baker, Khadilah H. M. Al-Furaiji, O. Tara Liyanage, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Chem. -Eur. J., 2019, 25, 1581-1587. Link
37. “Investigating the Reactivity of 9-Phenyl-9-Borafluorene with N-H, O-H, P-H, and S-H Bonds” L. E. Laperriere, S. Yruegas, C. D. Martin,* Tetrahedron, 2019, 75, 937-943. (Special Issue on Frustrated Lewis Acids and Organoboranes) Link
36. “Coordination and Ring Expansion of 1,2-Dipolar Molecules with 9-Phenyl-9-Borafluorene” Kristen R. Bluer#, Leif E. Laperriere#, Alba Pujol#, Sam Yruegas, Venkata A. K. Adiraju, Caleb D. Martin,* Organometallics, 2018, 37, 2917-2927. # Equal Contribution Link
35. “Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9-Borafluorene” Sam Yruegas, Jonathan H. Barnard, Khalidah Al-Furaiji, Jason L. Dutton, David J. D. Wilson, Caleb D. Martin,* Organometallics, 2018, 37, 1515-1518. Link
34. “Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis” Cheng-Liang Zhu, Cheng Wang, Qi-Xue Qin, Sam Yruegas, Caleb D. Martin, Hao Xu,* ACS Catalysis, 2018, 8, 5032-5037. Link
33. “Intermolecular Insertion Reactions of Azides Into 9-Borafluorenes to Generate 9,10-B,N-Phenanthrenes” Sam Yruegas, Jesse J. Martinez, Caleb D. Martin,* Chem. Commun., 2018, 54, 6808-6811. (Invited for Special Issue Entitled “Emerging Investigators 2018”) Link
32. “Isomer Dependence on the Reactivity of Diazenes with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin,* Chem. -Eur. J., 2017, 23, 11437-11444. Link
31. “Exploiting Pincer Ligands to Perturb the Geometry at Boron” Kexuan Huang, Jason L. Dutton, Caleb D. Martin,* Chem. -Eur. J., 2017, 23, 10532-10535. Link
30. “C-H Addition Reactivity of 2-Phenylpyridine and 2,2’-Bipyridine with Pentaphenylborole” Venkata A. K. Adiraju, Caleb D. Martin,* Dalton Trans., 2017, 46, 10324-10331. Link
29. “Ring Opening of Epoxides Induced by Pentaphenylborole” Sam Yruegas, Charles Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2017, 36, 2581-2587. (Invited for Special Issue Entitled “Tailoring the Optoelectronic Properties of Organometallic Compounds with Main Group Elements”) Link
28. “Expedient Synthesis of 1,2-Thiaborines via Sulfur Insertion into Boroles” Sam Yruegas, Caleb D. Martin,* Chem. -Eur. J., 2016, 22, 18358-18361. (Selected as a Hot Paper) Link
27. “Ring Expansion Reactions of Anti-Aromatic Boroles: A Promising Synthetic Avenue to Unsaturated Boracycles” Jonathan H. Barnard, Sam Yruegas, Kexuan Huang, Caleb D. Martin,* Chem. Commun., 2016, 52, 9985-9991. (Featured on the Inside Cover) Link
26. “Oxygen Insertion into Boroles as a Route to 1,2-Oxaborines” Sam Yruegas, Dayna C. Patterson, Caleb D. Martin,* Chem. Commun., 2016, 52, 6658-6661. (Featured on the Inside Cover) Link
25. “Reactivity of a Phosphaalkyne with Pentaarylboroles” Jonathan H. Barnard, Sam Yruegas, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Organometallics, 2016, 35, 929-931. Link
24. “Peculiar Reactivity of Isothiocyanates with Pentaphenylborole” Kexuan Huang, Caleb D. Martin,* Inorg. Chem., 2016, 55, 330-337. Link
23. “Probing the Reactivity of Pentaphenylborole with N-H, O-H, P-H, and S-H Bonds” Sam Yruegas, Kexuan Huang, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Dalton Trans., 2016, 45, 9902-9911. (Invited for Special Issue Entitled “New Talent: Americas”) Link
22. “Reactions of Pentaphenylborole with Main Group Hydrides” Ben C. Caputo, Zackery J. Manning, Jonathan H. Barnard, Caleb D. Martin,* Polyhedron, 2016, 114, 273-277. (Invited for Special Issue Entitled “Undergraduate Research in Inorganic Chemistry”) Link21. “1,2-Phosphaborines: Hybrid Inorganic/Organic P-B Analogues of Benzene” Jonathan H. Barnard, Paul A. Brown, Kevin L. Shuford, Caleb D. Martin,* Angew. Chem. Int. Ed., 2015, 54, 12083-12086. Link
20. “Reactions of Imines, Nitriles, and Isocyanides with Pentaphenylborole: Coordination, Ring Expansion, C-H Bond Activation, and Hydrogen Migration Reactions” Kexuan Huang, Shannon A. Couchman, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Inorg. Chem., 2015, 54, 8957-8968. Link
19. “Ring Expansion Reactions of Pentaphenylborole with Dipolar Molecules as a Route to Seven-Membered Boron Heterocycles” Kexuan Huang, Caleb D. Martin,* Inorg. Chem., 2015, 54, 1869-1875. Link
18. “Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide” Shannon A. Couchman, Trevor K. Thompson, David J. D. Wilson, Jason L. Dutton, Caleb D. Martin,* Chem. Commun., 2014, 11724-11726. Link