Research

Plasmonics and Nanophotonics
triprismNoble metal nanostructures support surface plasmon excitations that result from the collective oscillation of loosely bound electrons. At the resonant frequencies, the metal is highly polarizable and obtains large field-induced polarizations that radiate. Plasmon excitation can generate surface fields that are many orders of magnitude larger than the electromagnetic field applied initially. We are using methods based on classical electrodynamics to investigate metal nanoparticles and complex nanoscale architectures for various applications. Current projects include studies of nanoparticle optical properties, energy transfer in strongly coupled nanosystems, and molecular properties in close proximity to metallic surfaces.

 

Low Dimensional Nanomaterials
N1_Charge4The properties of nanomaterials are often strikingly different than both the molecular level and macroscopic regime.  Reducing dimensionality or system size from that of bulk can affect the material properties in fascinating and unusual ways.  We are using various electronic structure methods to examine the electronic and optical properties of nanomaterials.  Examples of targeted systems include semiconductor quantum dots, metal nanoparticles, and 2D materials.  We utilize both molecular quantum chemistry approaches with localized basis sets as well as plane wave density functional theory to understand bonding, structure, and reactivity.  The contour plot shows the electronic density of a nitrogen-doped graphene sheet.  There is a localization of charge at the lattice site where nitrogen is substituted for carbon.

 

Photovoltaics and Electrical Energy Storage
Solar energy is an attractive alternative to combustion fuels; however, photovoltaic devices are still plagued by high prices and low efficiencies. Moreover, energy generated from renewable sources often suffers from a disconnect between energy production and consumer usage, highlighting an additional need for cost effective and efficient electrical energy storage. Our group is investigating the properties of unique nano-architectures for use in photovoltaic devices. The interplay between plasmonic components, semiconducting surfaces, and donor-pi-acceptor molecules is of particular interest.  We are also investigating how energy is stored in supercapacitors and batteries to determine the link between interfacial chemistry and storage properties. We want to understand the processes occurring at the electrode/electrolyte interface on a molecular level to achieve higher energy and power densities in these devices. Currently, the focus is on aqueous electrolytes interacting with porous carbon electrodes to determine how confinement and hydration affect ion diffusivities, structured layer formation, and capacitance. Future work will involve investigating organic solutions and ionic liquids as electrolytes, and utilizing new electrode materials to further enhance electrical energy storage capabilities.

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Photocatalysis and Solar Fuels
Photocatalysts use solar photons to drive surface redox reactions that can create chemical fuels. The energy of sunlight is effectively harnessed by the photocatalyst and stored in chemical bonds that can be extracted later as needed.  The material absorbs photons with an energy greater than the band gap, which promotes electrons to the conduction band and leaves behind holes in the valence band.  Charge carriers migrate to interfaces and can participate in redox chemistry with adsorbed species.  Negatively-charged electrons will reduce acceptors, and positive holes can oxidize donors if certain conditions are met.  Specifically, the conduction band potential should be more negative, and valance band potential more positive, than the electrochemical potentials of desired reactions.  An alternate – and less attractive outcome – is charge carrier recombination that generates heat and emission.  Our group is modeling photocatalyst heterojunctions composed of metal-free 2D materials as alternatives to titania-based systems.

 

 

 

Recent Cover Art

 

We graciously thank our sponsors for research funding.

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